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Issue 22, 2015
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Towards synergy between spin-crossover and metal–ligand bond break in molecular crystals: structural investigations of eight seven-coordinated Fe(II) macrocyclic complexes

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Abstract

Sixteen structures of eight analogical Fe(II) macrocyclic complexes have been investigated exhibiting distinguishable structural properties even though no spin-crossover is observed. Notwithstanding, due to a synergistic effect between ligand field strength and intermolecular interaction, two of these complexes present very rare evidence for metal–ligand bond break at low temperature.

Graphical abstract: Towards synergy between spin-crossover and metal–ligand bond break in molecular crystals: structural investigations of eight seven-coordinated Fe(ii) macrocyclic complexes

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Publication details

The article was received on 18 Mar 2015, accepted on 17 Apr 2015 and first published on 20 Apr 2015


Article type: Communication
DOI: 10.1039/C5CE00557D
Citation: CrystEngComm, 2015,17, 4075-4079

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    Towards synergy between spin-crossover and metal–ligand bond break in molecular crystals: structural investigations of eight seven-coordinated Fe(II) macrocyclic complexes

    H. Wang, A. Grosjean, C. Sinito, A. Kaiba, C. Baldé, C. Desplanches, J. Létard and P. Guionneau, CrystEngComm, 2015, 17, 4075
    DOI: 10.1039/C5CE00557D

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