Predicting and creating 7-connected Zn4O vertices for the construction of an exceptional metal–organic framework with nanoscale cages

Shizhe Bai; Weiquan Zhang; Yun Ling; Feilong Yang; Mingli Deng; Zhenxia Chen; Linhong Weng; Yaming Zhou

doi:10.1039/C4CE02415J

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Predicting and creating 7-connected Zn₄O vertices for the construction of an exceptional metal–organic framework with nanoscale cages†

Shizhe Bai,^a Weiquan Zhang,^a Yun Ling,^a Feilong Yang,^a Mingli Deng,*^a Zhenxia Chen,^a Linhong Weng^a and Yaming Zhou*^a

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* Corresponding authors

^a Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai, China
E-mail: mldeng@fudan.edu.cn, ymzhou@fudan.edu.cn
Fax: +86 21 65643925
Tel: +86 21 65642261

Abstract

A 7-connected Zn₄O unit has been theoretically predicted based on the model of basic zinc acetate [Zn₄O(CH₃COO)₆], which was then experimentally extended into a three-dimensional structure featuring three kinds of nanocage in a unit cell.

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Article information

DOI: https://doi.org/10.1039/C4CE02415J
Article type: Communication
Submitted: 06 Dec 2014
Accepted: 23 Jan 2015
First published: 26 Jan 2015

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CrystEngComm, 2015,17, 1923-1926

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Predicting and creating 7-connected Zn₄O vertices for the construction of an exceptional metal–organic framework with nanoscale cages

S. Bai, W. Zhang, Y. Ling, F. Yang, M. Deng, Z. Chen, L. Weng and Y. Zhou, CrystEngComm, 2015, 17, 1923 DOI: 10.1039/C4CE02415J

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