Through a careful design of the molecular precursor we have successfully constructed the metal–organic Sierpiński triangles on Au(111) via on-surface coordination chemistry, which is demonstrated by the interplay of high-resolution STM imaging and DFT calculations. The coordination Sierpiński triangles show high stabilities as evidenced by room temperature STM imaging, and could withstand a thermal treatment up to 450 K.
Q. Sun, L. Cai, H. Ma, C. Yuan and W. Xu, Chem. Commun., 2015, 51, 14164 DOI: 10.1039/C5CC05554G
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