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Issue 61, 2015
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UV photoexcitation of a dissolved metalloid Ge9 cluster compound and its extensive ultrafast response

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Abstract

Femtosecond pump–probe absorption spectroscopy in tetrahydrofuran solution has been used to investigate the dynamics of a metalloid cluster compound {Ge9[Si(SiMe3)3]3}1. Upon UV photoexcitation, the transients in the near-infrared spectral region showed signatures reminiscent of excess electrons in THF (bound or quasi-free) whereas in the visible part excited state dynamics of the cluster complex dominates.

Graphical abstract: UV photoexcitation of a dissolved metalloid Ge9 cluster compound and its extensive ultrafast response

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Supplementary files

Article information


Submitted
02 Jun 2015
Accepted
27 Jun 2015
First published
03 Jul 2015

Chem. Commun., 2015,51, 12278-12281
Article type
Communication
Author version available

UV photoexcitation of a dissolved metalloid Ge9 cluster compound and its extensive ultrafast response

M. Klinger, C. Schenk, F. Henke, A. Clayborne, A. Schnepf and A.-N. Unterreiner, Chem. Commun., 2015, 51, 12278
DOI: 10.1039/C5CC04513D

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