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Issue 41, 2015
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Estimation of bonding nature using diamagnetic susceptibility

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Abstract

A chemical bond includes both covalent and ionic characteristics. We develop an experimental method to estimate the degree of each contribution based on magnetic susceptibility measurements, in which Pascal's scheme for Larmor diamagnetism is combined with electronegativity. The applicability to metal hydrides is also shown.

Graphical abstract: Estimation of bonding nature using diamagnetic susceptibility

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Publication details

The article was received on 20 Mar 2015, accepted on 15 Apr 2015 and first published on 24 Apr 2015


Article type: Communication
DOI: 10.1039/C5CC02351C
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Chem. Commun., 2015,51, 8691-8694

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    Estimation of bonding nature using diamagnetic susceptibility

    K. Tomiyasu, T. Sato and S. Orimo, Chem. Commun., 2015, 51, 8691
    DOI: 10.1039/C5CC02351C

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