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Issue 16, 2015
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Poly(vinyl ester 1,2,3-triazolium)s: a new member of the poly(ionic liquid)s family

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Abstract

A vinyl ester monomer carrying a pendant 1,2,3-triazole group is synthesized in two steps and polymerized by cobalt-mediated radical polymerization. Subsequent alkylation with N-methyl bis[(trifluoromethyl)sulfonyl]imide affords the corresponding poly(vinyl ester 1,2,3-triazolium). This unprecedented example of poly(vinyl ester ionic liquid) exhibits an ionic conductivity of 9.2 × 10−7 S cm−1 at 30 °C.

Graphical abstract: Poly(vinyl ester 1,2,3-triazolium)s: a new member of the poly(ionic liquid)s family

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Publication details

The article was received on 05 Nov 2014, accepted on 07 Jan 2015 and first published on 08 Jan 2015


Article type: Communication
DOI: 10.1039/C4CC08847F
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Citation: Chem. Commun., 2015,51, 3332-3335

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    Poly(vinyl ester 1,2,3-triazolium)s: a new member of the poly(ionic liquid)s family

    M. M. Obadia, G. Colliat-Dangus, A. Debuigne, A. Serghei, C. Detrembleur and E. Drockenmuller, Chem. Commun., 2015, 51, 3332
    DOI: 10.1039/C4CC08847F

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