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Issue 99, 2015
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Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

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Abstract

A nitro-substituted dipyrrolylphenol was synthesized as a precursor of a π-electronic anion, whose phenolate (phenoxide) moiety upon deprotonation was stabilized by the hydrogen-bond-donating pyrrole NH, thus forming solid-state ion pairs with various cationic species.

Graphical abstract: Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

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Publication details

The article was received on 07 Sep 2015, accepted on 12 Oct 2015 and first published on 14 Oct 2015


Article type: Communication
DOI: 10.1039/C5CC07493B
Citation: Chem. Commun., 2015,51, 17572-17575
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    Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

    H. Maeda, A. Fukui, R. Yamakado and N. Yasuda, Chem. Commun., 2015, 51, 17572
    DOI: 10.1039/C5CC07493B

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