SCHEDULED MAINTENANCE
Enantiomeric M4L4 helical cages have been prepared whose supramolecular chirality is induced by the chemical chirality of the self-sorting amino acid-derived ligands that are used. Using scrambled diastereomeric ligands or achiral glycine-derived ligands yields analogous complexes yet ‘turns off’ the supramolecular chirality by producing centrosymmetric cages.
S. A. Boer and D. R. Turner, Chem. Commun., 2015, 51, 17375 DOI: 10.1039/C5CC07422C
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