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Issue 84, 2015
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Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition

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Abstract

The first example of phototunable SMMs has been reported. Upon UV irradiation, variations of the coordination sphere around Dy(III) ions actually affect the magnetic behaviour of the compound via [2+2] cycloaddition reaction, leading to a magnetic transformation from the SMM behaviour to a field-induced slow relaxation.

Graphical abstract: Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition

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Publication details

The article was received on 22 Aug 2015, accepted on 03 Sep 2015 and first published on 03 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC07073B
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Chem. Commun., 2015,51, 15358-15361

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    Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition

    L. Wang, J. Qiu, J. Liu, Y. Chen, J. Jia, J. Jover, E. Ruiz and M. Tong, Chem. Commun., 2015, 51, 15358
    DOI: 10.1039/C5CC07073B

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