Issue 83, 2015
From the journal:

Chemical Communications

The influence of imperfect walls on the guest binding properties of hydrogen-bonded capsules†

Chang-You Zhu,‡ab   Hao-Yi Wang,‡b   Jiao-Nan Sun,b   Gang Ye,b   Julius Rebek, Jr.*cd  and  Wei Jiang*b  

* Corresponding authors

a School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, P. R. China

b Department of Chemistry, South University of Science and Technology of China, No. 1088 Xueyuan Blvd, Nanshan District, Shenzhen, P. R. China
E-mail: jiangw@sustc.edu.cn
Tel: +86-755-88018316

c Department of Chemistry, Fudan University, 220 Handan Road, Shanghai, P. R. China

d The Skaggs Institute for Chemical Biology and Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA
E-mail: jrebek@scripps.edu
Fax: +1-8587842876
Tel: +1-8587842250

Abstract

Three classes of hydrogen-bonded capsules with imperfect walls have been prepared and characterized. The defects reduce the symmetry of the capsules, leading to rich isomerism. The missing hydrogen bonds provide additional flexibility to the capsules and exert an influence on their guest binding properties in different assemblies.

Graphical abstract: The influence of imperfect walls on the guest binding properties of hydrogen-bonded capsules

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Article information

DOI
https://doi.org/10.1039/C5CC06727H
Article type
Communication
Submitted
11 Aug 2015
Accepted
21 Aug 2015
First published
24 Aug 2015

Chem. Commun., 2015,51, 15276-15279

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The influence of imperfect walls on the guest binding properties of hydrogen-bonded capsules

C. Zhu, H. Wang, J. Sun, G. Ye, J. Rebek and W. Jiang, Chem. Commun., 2015, 51, 15276 DOI: 10.1039/C5CC06727H

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