Issue 100, 2015

One-dimensional coordination polymers of [Co3(dpa)4]2+ and [MF6]2− (M = ReIV, ZrIV and SnIV)

Abstract

One-dimensional coordination polymers of alternating metal–metal bonded trinuclear [Co3(dpa)4]2+ (dpa = the anion of 2,2′-dipyridylamine) building blocks and [ReF6]2− (1), [ZrF6]2− (2) or [SnF6]2− (3) linkers have been self-assembled and crystallographically characterized. Magnetic measurements reveal a significant ferromagnetic coupling (J/kB = +9.9 K) between S = 1/2 {Co36+} and S = 3/2 ReIV magnetic sites through a single, unsupported fluoride bridge in 1.

Graphical abstract: One-dimensional coordination polymers of [Co3(dpa)4]2+ and [MF6]2− (M = ReIV, ZrIV and SnIV)

Supplementary files

Article information

Article type
Communication
Submitted
10 Aug 2015
Accepted
16 Oct 2015
First published
16 Oct 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 17748-17751

Author version available

One-dimensional coordination polymers of [Co3(dpa)4]2+ and [MF6]2− (M = ReIV, ZrIV and SnIV)

V. Bulicanu, K. S. Pedersen, M. Rouzières, J. Bendix, P. Dechambenoit, R. Clérac and E. A. Hillard, Chem. Commun., 2015, 51, 17748 DOI: 10.1039/C5CC06704A

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