Issue 94, 2015
From the journal:

Chemical Communications

Complete hydrogen release from aqueous ammonia-borane over a platinum-loaded titanium dioxide photocatalyst†

Takashi Kamegawa*a  and  Takayuki Nakaueab  

* Corresponding authors

a Nanoscience and Nanotechnology Research Center, Osaka Prefecture University, 1-2 Gakuencho, Nakaku, Sakai, Osaka 599-8570, Japan
E-mail: t-kamegawa@21c.osakafu-u.ac.jp
Fax: +81-72-254-9709
Tel: +81-72-254-9709

b Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuencho, Nakaku, Sakai, Osaka 599-8531, Japan

Abstract

Complete H2 release from ammonia-borane (NH3BH3, AB) in water was achieved by using platinum-loaded TiO2 (Pt/TiO2) via two consecutive reaction steps, i.e., hydrolysis of AB and photocatalytic decomposition of thus formed NH3 in water, under inert conditions at 298 K.

Graphical abstract: Complete hydrogen release from aqueous ammonia-borane over a platinum-loaded titanium dioxide photocatalyst

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Article information

DOI
https://doi.org/10.1039/C5CC06639E
Article type
Communication
Submitted
07 Aug 2015
Accepted
22 Sep 2015
First published
22 Sep 2015

Chem. Commun., 2015,51, 16802-16805

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Complete hydrogen release from aqueous ammonia-borane over a platinum-loaded titanium dioxide photocatalyst

T. Kamegawa and T. Nakaue, Chem. Commun., 2015, 51, 16802 DOI: 10.1039/C5CC06639E

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