Issue 90, 2015
From the journal:

Chemical Communications

Phosphine-catalyzed regioselective Michael addition to allenoates†

Vasudeva Rao Gandia  and  Yixin Lu*a  

* Corresponding authors

a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Republic of Singapore 117543
E-mail: chmlyx@nus.edu.sg

Abstract

The first phosphine catalysed Michael addition of arylcyanoacetates to allenoates has been developed, and the β-selective products with a quaternary center were obtained in excellent yields. This unusual regioselectivity may open new opportunities to access interesting molecular structures.

Graphical abstract: Phosphine-catalyzed regioselective Michael addition to allenoates

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Article information

DOI
https://doi.org/10.1039/C5CC06197K
Article type
Communication
Submitted
24 Jul 2015
Accepted
09 Sep 2015
First published
09 Sep 2015

Chem. Commun., 2015,51, 16188-16190

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Phosphine-catalyzed regioselective Michael addition to allenoates

V. R. Gandi and Y. Lu, Chem. Commun., 2015, 51, 16188 DOI: 10.1039/C5CC06197K

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