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Issue 94, 2015
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Synthesis of highly strained bicyclic[3.n.1]alkenes by a metal-catalyzed Conia-ene reaction

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Abstract

A high yielding metal-catalysed Conia-ene reaction of 2-acetylenic ketones for the synthesis of bicyclo[3.n.1]alkenes has been developed. This simple and efficient 6-endo-dig-cyclization protocol enables the synthesis of a wide variety of bicyclic systems, present in many natural products.

Graphical abstract: Synthesis of highly strained bicyclic[3.n.1]alkenes by a metal-catalyzed Conia-ene reaction

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Publication details

The article was received on 16 Jul 2015, accepted on 18 Sep 2015 and first published on 21 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC05926G
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Citation: Chem. Commun., 2015,51, 16840-16843

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    Synthesis of highly strained bicyclic[3.n.1]alkenes by a metal-catalyzed Conia-ene reaction

    S. Kallepu, K. K. Gollapelli, J. B. Nanubolu and R. Chegondi, Chem. Commun., 2015, 51, 16840
    DOI: 10.1039/C5CC05926G

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