Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 80, 2015
Previous Article Next Article

Novel mode of 2-fold interpenetration observed in a primitive cubic network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n

Author affiliations

Abstract

A primitive cubic (pcu) network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n, DICRO-2-Ni-i, has been synthesised and found to exhibit a novel type of inclined 2-fold interpenetration and an isosteric heat of adsorption (Qst) of 30.5 kJ mol−1 towards CO2 at zero loading. Qst is relatively high in the broad context but less than that observed in related hybrid ultramicroporous materials, a feature that can be understood after studying pore structure and molecular simulations of CO2 adsorption.

Graphical abstract: Novel mode of 2-fold interpenetration observed in a primitive cubic network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n

Back to tab navigation

Supplementary files

Article information


Submitted
15 Jul 2015
Accepted
19 Aug 2015
First published
19 Aug 2015

Chem. Commun., 2015,51, 14832-14835
Article type
Communication
Author version available

Novel mode of 2-fold interpenetration observed in a primitive cubic network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n

H. S. Scott, A. Bajpai, K. Chen, T. Pham, B. Space, J. J. Perry and M. J. Zaworotko, Chem. Commun., 2015, 51, 14832
DOI: 10.1039/C5CC05866J

Social activity

Search articles by author

Spotlight

Advertisements