Issue 78, 2015
From the journal:

Chemical Communications

Differentially functionalized acyclic cucurbiturils: synthesis, self-assembly and CB[6]-induced allosteric guest binding†

Mingming Zhang,a   David Sigwalta  and  Lyle Isaacs*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Maryland, College Park, USA
E-mail: LIsaacs@umd.edu
Fax: +1-301-314-9121
Tel: +1-301-405-1884

Abstract

We report the synthesis of mono- and difunctionalized acyclic cucurbit[n]uril-type containers (1HA, 1HDA, 2HDA) which bear hexylammonium and hexanediammonium arms. The intra- and intermolecular assembly processes of 1HA, 1HDA, 2HDA as well as the ability of CB[n] to trigger allosteric host–guest binding toward guests 9–11 are presented.

Graphical abstract: Differentially functionalized acyclic cucurbiturils: synthesis, self-assembly and CB[6]-induced allosteric guest binding

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Article information

DOI
https://doi.org/10.1039/C5CC05803A
Article type
Communication
Submitted
13 Jul 2015
Accepted
11 Aug 2015
First published
13 Aug 2015

Chem. Commun., 2015,51, 14620-14623

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Differentially functionalized acyclic cucurbiturils: synthesis, self-assembly and CB[6]-induced allosteric guest binding

M. Zhang, D. Sigwalt and L. Isaacs, Chem. Commun., 2015, 51, 14620 DOI: 10.1039/C5CC05803A

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