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Issue 78, 2015
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Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

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Abstract

The first examples of halogen bonding redox-active ferrocene receptors and their anion electrochemical sensing properties are reported. Halogen bonding was found to significantly amplify the magnitude of the receptor's metallocene redox-couple's voltammetric responses for halide sensing compared to their hydrogen bonding analogues in both acetonitrile and aqueous–acetonitrile solvent media.

Graphical abstract: Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

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Publication details

The article was received on 09 Jul 2015, accepted on 05 Aug 2015 and first published on 06 Aug 2015


Article type: Communication
DOI: 10.1039/C5CC05704C
Citation: Chem. Commun., 2015,51, 14640-14643
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    Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

    J. Y. C. Lim, M. J. Cunningham, J. J. Davis and P. D. Beer, Chem. Commun., 2015, 51, 14640
    DOI: 10.1039/C5CC05704C

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