Issue 80, 2015
From the journal:

Chemical Communications

Bisalkynylated 3,6-diiminocyclohexa-1,4-diene-1,4-diamine†

Philipp Biegger,‡a   Manuel Schaffroth,‡a   Kerstin Brödner,a   Olena Tverskoy,a   Frank Romingera  and  Uwe H. F. Bunz*ab  

* Corresponding authors

a Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany
E-mail: uwe.bunz@oci.uni-heidelberg.de
Fax: +49-6221548401

b Centre for Advanced Materials, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 225, 69120 Heidelberg, Germany

Abstract

Reduction of bis(benzothiadiazol) by LiAlH4/CuI gives diethynylated diaminobenzoquinoneimine. This building block accesses novel targets in a one-step condensation reaction with different ortho-quinones, resulting in unexpected rearrangement products. The compounds are characterized by their photophysical and electrochemical data as well as quantum chemical calculations.

Graphical abstract: Bisalkynylated 3,6-diiminocyclohexa-1,4-diene-1,4-diamine

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5CC05427C
Article type
Communication
Submitted
02 Jul 2015
Accepted
15 Jul 2015
First published
21 Jul 2015

Chem. Commun., 2015,51, 14844-14847

Permissions

Request permissions

Bisalkynylated 3,6-diiminocyclohexa-1,4-diene-1,4-diamine

P. Biegger, M. Schaffroth, K. Brödner, O. Tverskoy, F. Rominger and U. H. F. Bunz, Chem. Commun., 2015, 51, 14844 DOI: 10.1039/C5CC05427C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements