Issue 87, 2015
From the journal:

Chemical Communications

Construction of a porous three dimensional rare earth metal–sulfur–ligand open framework†

Jin Xu,a   Ting Liu,ab   Xiaohui Han,ab   Shanshan Wang,ab   Dan Liu*a  and  Cheng Wang*a  

* Corresponding authors

a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, P. R. China
E-mail: liudan2007@ciac.ac.cn, cwang@ciac.ac.cn

b University of Chinese Academy of Sciences, Beijing 100039, P. R. China

Abstract

A slow reaction between Nd3+ and piperazine-1,4-dicarbodithiolate disodium (Na2(pipzdtc)) affords a three dimensional (3D) anionic [Nd(pipzdtc)2]nn− framework with a dia net. The encapsulated disordered guest molecules could be partially exchanged by Ni2+ accompanied by the quenching of the typical NIR luminescence of Nd3+ ions.

Graphical abstract: Construction of a porous three dimensional rare earth metal–sulfur–ligand open framework

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5CC05371D
Article type
Communication
Submitted
30 Jun 2015
Accepted
28 Aug 2015
First published
28 Aug 2015

Chem. Commun., 2015,51, 15819-15822

Permissions

Request permissions

Construction of a porous three dimensional rare earth metal–sulfur–ligand open framework

J. Xu, T. Liu, X. Han, S. Wang, D. Liu and C. Wang, Chem. Commun., 2015, 51, 15819 DOI: 10.1039/C5CC05371D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements