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Issue 87, 2015
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Cyclometalated (boroxinato)gold(III) complexes from arrested transmetalation

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Abstract

Organic boroxines are ubiquitous, but metallaboroxine analogues remain rare. A new class of (boroxinato)gold species are demonstrated here, as are observations of phosphorescence from boroxinato complexes. Four new compounds are crystallographically characterized.

Graphical abstract: Cyclometalated (boroxinato)gold(iii) complexes from arrested transmetalation

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The article was received on 24 Jun 2015, accepted on 08 Sep 2015 and first published on 08 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC05200A
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Citation: Chem. Commun., 2015,51, 15800-15803
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    Cyclometalated (boroxinato)gold(III) complexes from arrested transmetalation

    A. R. Browne, N. Deligonul, B. L. Anderson, M. Zeller, A. D. Hunter and T. G. Gray, Chem. Commun., 2015, 51, 15800
    DOI: 10.1039/C5CC05200A

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