Issue 68, 2015

Salts of the two-coordinate homoleptic manganese(i) dialkyl anion [Mn{C(SiMe3)3}2] with quenched orbital magnetism

Abstract

The reduction of Mn{C(SiMe3)3}2 with KC8 in the presence of crown ethers yielded the d6, Mn(I) salts [K2(18-crown-6)3][Mn{C(SiMe3)3}2]2 and [K(15-crown-5)2][Mn{C(SiMe3)3}2], that have near-linear manganese coordination but almost completely quenched orbital magnetism as a result of 4s–3dz2 orbital mixing which affords a non-degenerate ground state.

Graphical abstract: Salts of the two-coordinate homoleptic manganese(i) dialkyl anion [Mn{C(SiMe3)3}2]− with quenched orbital magnetism

Supplementary files

Article information

Article type
Communication
Submitted
23 Jun 2015
Accepted
05 Jul 2015
First published
07 Jul 2015

Chem. Commun., 2015,51, 13275-13278

Salts of the two-coordinate homoleptic manganese(I) dialkyl anion [Mn{C(SiMe3)3}2] with quenched orbital magnetism

C.-Y. Lin, J. C. Fettinger, N. F. Chilton, A. Formanuik, F. Grandjean, G. J. Long and P. P. Power, Chem. Commun., 2015, 51, 13275 DOI: 10.1039/C5CC05166E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements