Controlling the flexibility and single-crystal to single-crystal interpenetration reconstitution of metal–organic frameworks

Dong-Dong Zhou; Zhi-Juan Liu; Chun-Ting He; Pei-Qin Liao; Hao-Long Zhou; Zhen-Song Zhong; Rui-Biao Lin; Wei-Xiong Zhang; Jie-Peng Zhang; Xiao-Ming Chen

doi:10.1039/C5CC05036G

Controlling the flexibility and single-crystal to single-crystal interpenetration reconstitution of metal–organic frameworks†

Dong-Dong Zhou,^a Zhi-Juan Liu,^a Chun-Ting He,^a Pei-Qin Liao,^a Hao-Long Zhou,^a Zhen-Song Zhong,^a Rui-Biao Lin,^a Wei-Xiong Zhang,^a Jie-Peng Zhang*^a and Xiao-Ming Chen^a

Author affiliations

* Corresponding authors

^a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: zhangjp7@mail.sysu.edu.cn

Abstract

By changing the ligand substituent groups near the open metal sites from hydrophilic to hydrophobic, the guest-induced structural dynamism of a series of isostructural 5-fold interpenetrated MOFs changed from interpenetration reconstitution to simple framework breathing.

Chemical Communications

Controlling the flexibility and single-crystal to single-crystal interpenetration reconstitution of metal–organic frameworks†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Controlling the flexibility and single-crystal to single-crystal interpenetration reconstitution of metal–organic frameworks

Social activity

Search articles by author

Spotlight

Advertisements