Hybrid materials of Ni NP@MOF prepared by a simple synthetic method

Megumi Mukoyoshi; Hirokazu Kobayashi; Kohei Kusada; Mikihiro Hayashi; Teppei Yamada; Mitsuhiko Maesato; Jared M. Taylor; Yoshiki Kubota; Kenichi Kato; Masaki Takata; Tomokazu Yamamoto; Syo Matsumura; Hiroshi Kitagawa

doi:10.1039/C5CC04663G

Hybrid materials of Ni NP@MOF prepared by a simple synthetic method†

Megumi Mukoyoshi,^a Hirokazu Kobayashi,*^ab Kohei Kusada,^ab Mikihiro Hayashi,^a Teppei Yamada,

‡^a Mitsuhiko Maesato,^a Jared M. Taylor,^ab Yoshiki Kubota,^c Kenichi Kato,^de Masaki Takata,^de Tomokazu Yamamoto,^bf Syo Matsumura^bfg and Hiroshi Kitagawa*^abhi

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* Corresponding authors

^a Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan
E-mail: hkobayashi@kuchem.kyoto-u.ac.jp, kitagawa@kuchem.kyoto-u.ac.jp

^b JST CREST, 7, Gobancho, Chiyoda-ku, Tokyo 102-0076, Japan

^c Department of Physical Science, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan

^d RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan

^e Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan

^f Department of Applied Quantum Physics and Nuclear Engineering, Graduate School of Engineering, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan

^g Research Laboratory for High-Voltage Electron Microscopy, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan

^h Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

ⁱ INAMORI Frontier Research Center, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

We demonstrate a novel, simple synthetic method for metal (Ni) NPs in a MOF using the partial thermal decomposition of nickel(II) 2,5-dihydroxyterephthalate (Ni-MOF-74). The Ni NPs inside the Ni-MOF-74 are several nanometers in size, and the size can be precisely controlled by the heating conditions.

Chemical Communications

Hybrid materials of Ni NP@MOF prepared by a simple synthetic method†

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