SCHEDULED MAINTENANCE
1,3,5-Triethylbenzene based tripodal trisilanols were synthesized. The X-ray crystal structures of trisilanols showed capsule formation as well as non-capsular network formation using silanol hydrogen bonds. The 1H NMR and ESI-mass spectroscopy experiments for solution state binding supported encapsulation of the halide ions in the cavity of the molecular capsule with a C3 symmetry.
M. Fukawa, T. Sato and Y. Kabe, Chem. Commun., 2015, 51, 14746 DOI: 10.1039/C5CC04515K
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