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Issue 58, 2015
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A Cu(ii)-based strategy for catalytic enantioselective β-borylation of α,β-unsaturated acceptors

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Abstract

Cu(I)-based chemistry has flourished over the last decade because of the reliable use of species such as soft acids. However, the unique nature of Cu(II) catalysts allows the well-documented Cu(I)-based chemistry to be extended. Prominent advantages of this approach include the ease of handling, the avoidance of strong base, and a wider substrate scope in enantioselective β-borylation.

Graphical abstract: A Cu(ii)-based strategy for catalytic enantioselective β-borylation of α,β-unsaturated acceptors

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Article information


Submitted
26 May 2015
Accepted
10 Jun 2015
First published
10 Jun 2015

Chem. Commun., 2015,51, 11685-11688
Article type
Communication

A Cu(II)-based strategy for catalytic enantioselective β-borylation of α,β-unsaturated acceptors

L. Zhu, T. Kitanosono, P. Xu and S. Kobayashi, Chem. Commun., 2015, 51, 11685
DOI: 10.1039/C5CC04295J

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