Issue 62, 2015
From the journal:

Chemical Communications

Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia†

Liliang Wang,‡a   Lingbing Kong,‡a   Yongxin Li,b   Rakesh Gangulyb  and  Rei Kinjo*a  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, Singapore
E-mail: rkinjo@ntu.edu.sg

b NTU-CBC Crystallography Facility, Nanyang Technological University, Nanyang Link 21, Singapore 637371, Singapore

Abstract

Gold-catalyzed hydroimination of terminal alkynes, giving rise to anti-Markovnikov adducts concomitant with unstable Markovnikov adducts is described. The elementary step can be applied for the construction of pyridine derivatives from ammonia and alkynes.

Graphical abstract: Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia

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Article information

DOI
https://doi.org/10.1039/C5CC04091D
Article type
Communication
Submitted
19 May 2015
Accepted
24 Jun 2015
First published
24 Jun 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 12419-12422

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Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia

L. Wang, L. Kong, Y. Li, R. Ganguly and R. Kinjo, Chem. Commun., 2015, 51, 12419 DOI: 10.1039/C5CC04091D

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