Issue 56, 2015
From the journal:

Chemical Communications

Mn(iii)-mediated phosphonation–azidation of alkenes: a facile synthesis of β-azidophosphonates†

Jian Xu,a   Xueqin Li,a   Yuzhen Gao,a   Liangliang Zhang,a   Weizhu Chen,ab   Hua Fang,b   Guo Tang*a  and  Yufen Zhaoa  

* Corresponding authors

a Department of Chemistry, College of Chemistry and Chemical Engineering, and the Key Laboratory for Chemical Biology of Fujian Province, Xiamen University, Xiamen, Fujian 361005, China
E-mail: t12g21@xmu.edu.cn
Fax: +86-592-2185780

b Third Institute of Oceanography, State Oceanic Administration, Xiamen, Fujian 361005, China

Abstract

A new and general method for the synthesis of β-azidophosphonates has been achieved through Mn(OAc)3-mediated radical oxidative phosphonation–azidation of alkenes. The starting materials of P(O)–H compounds, alkenes, and azidotrimethylsilane are stable and cheap. This method can be easily adapted for large-scale preparation.

Graphical abstract: Mn(iii)-mediated phosphonation–azidation of alkenes: a facile synthesis of β-azidophosphonates

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Article information

DOI
https://doi.org/10.1039/C5CC03995A
Article type
Communication
Submitted
14 May 2015
Accepted
03 Jun 2015
First published
03 Jun 2015

Chem. Commun., 2015,51, 11240-11243

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Mn(III)-mediated phosphonation–azidation of alkenes: a facile synthesis of β-azidophosphonates

J. Xu, X. Li, Y. Gao, L. Zhang, W. Chen, H. Fang, G. Tang and Y. Zhao, Chem. Commun., 2015, 51, 11240 DOI: 10.1039/C5CC03995A

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