The straightforward synthesis of new supramolecular metallacycles having a ‘pseudo double-paracyclophane’ structure is presented. They are obtained from the reaction of a pre-assembled Cu(I) bimetallic precursor bearing short intermetallic distances with cyano-capped homoditopic π-conjugated linkers having flexible central cores.
W. Shen, M. El Sayed Moussa, Y. Yao and C. Lescop, Chem. Commun., 2015, 51, 11560 DOI: 10.1039/C5CC03778F
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