Issue 55, 2015
From the journal:

Chemical Communications

Proton conduction in Mo(vi)-based metallo-supramolecular polymers†

Rakesh K. Pandey,a   Md. Delwar Hossain,a   Chanchal Chakraborty,a   Satoshi Moriyamabc  and  Masayoshi Higuchi*ac  

* Corresponding authors

a Electronic Functional Materials Group, National Institute for Materials Science (NIMS), Tsukuba 305-0044, Japan
E-mail: HIGUCHI.masayoshi@nims.go.jp

b International Centre for Materials Nanoarchitectonics (MANA), NIMS, Tsukuba, Japan

c JST-CREST, Japan

Abstract

High proton conduction (8.5 × 10−2 mS cm−1) was observed in a Mo(VI)-based metallo-supramolecular polymer with carboxylic acids at 95%RH. The integration of OH groups into the polymer was analysed using FTIR spectroscopy and found to be crucial for the proton transport in the polymer.

Graphical abstract: Proton conduction in Mo(vi)-based metallo-supramolecular polymers

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Article information

DOI
https://doi.org/10.1039/C5CC03634H
Article type
Communication
Submitted
01 May 2015
Accepted
21 May 2015
First published
21 May 2015

Chem. Commun., 2015,51, 11012-11014

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Proton conduction in Mo(VI)-based metallo-supramolecular polymers

R. K. Pandey, Md. Delwar Hossain, C. Chakraborty, S. Moriyama and M. Higuchi, Chem. Commun., 2015, 51, 11012 DOI: 10.1039/C5CC03634H

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