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Issue 57, 2015
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Dimeric platinum–stannylene complexes by twofold ligand transfer from an NHC adduct to an organotin(II) hydride

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Abstract

Upon ligand transfer of hydrides and NHC a dimeric formal Pt(I)–Sn(I) (2) complex was obtained from a 1 : 1 reaction of Pt(cod)2 (cod = 1,5-cyclooctadiene) and the NHC adduct to a bulky terphenyltin(II) hydride Ar*SnH(NHC) (1) [NHC = 1,3,4,5-tetramethylimidazol-2-ylidene, Ar* = 2,6-(2,4,6-triisopropylphenyl)C6H3]. The bridging stannylene Sn atoms each reveal an individual coordinative interaction with the platinum atoms and the hydrides with ‘non-classic’ Pt–H–Sn bonds.

Graphical abstract: Dimeric platinum–stannylene complexes by twofold ligand transfer from an NHC adduct to an organotin(ii) hydride

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Publication details

The article was received on 24 Apr 2015, accepted on 11 Jun 2015 and first published on 18 Jun 2015


Article type: Communication
DOI: 10.1039/C5CC03425F
Citation: Chem. Commun., 2015,51, 11421-11424
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    Dimeric platinum–stannylene complexes by twofold ligand transfer from an NHC adduct to an organotin(II) hydride

    C. P. Sindlinger and L. Wesemann, Chem. Commun., 2015, 51, 11421
    DOI: 10.1039/C5CC03425F

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