Issue 57, 2015

Heck–Mizoroki coupling of vinyliodide and applications in the synthesis of dienes and trienes

Abstract

Vinyliodide reacts chemoselectively under Heck–Mizoroki conditions with terminal alkenes, including vinylboronate esters, to give dienes. The resulting dienylboronates undergo Suzuki–Miyaura couplings with aryl, heteroaryl and alkenyl halides to access dienes and trienes.

Graphical abstract: Heck–Mizoroki coupling of vinyliodide and applications in the synthesis of dienes and trienes

Supplementary files

Article information

Article type
Communication
Submitted
20 Apr 2015
Accepted
10 Jun 2015
First published
11 Jun 2015

Chem. Commun., 2015,51, 11409-11412

Author version available

Heck–Mizoroki coupling of vinyliodide and applications in the synthesis of dienes and trienes

K. S. Madden, S. David, J. P. Knowles and A. Whiting, Chem. Commun., 2015, 51, 11409 DOI: 10.1039/C5CC03273C

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