Issue 50, 2015
From the journal:

Chemical Communications

Cationic dinuclear platinum and palladium complexes with bridging hydrogermylene and hydrido ligands†

Norio Nakata,a   Noriko Sekizawaa  and  Akihiko Ishii*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama, Japan
E-mail: ishiiaki@chem.saitama-u.ac.jp

Abstract

Hydride-abstraction reactions of hydrido(dihydrogermyl) complexes [MH(GeH2Trip)(dcpe)] [M = Pt, Pd, Trip = 9-triptycyl, dcpe = 1,2-bis(dicyclohexylphosphino)ethane] with B(C6F5)3 led to the unexpected formation of new cationic (μ-germyl)(μ-hydrido) dinuclear platinum and palladium complexes, [{M(dcpe)}2(μ-GeHTrip)(μ-H)]+.

Graphical abstract: Cationic dinuclear platinum and palladium complexes with bridging hydrogermylene and hydrido ligands

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Article information

DOI
https://doi.org/10.1039/C5CC03062E
Article type
Communication
Submitted
13 Apr 2015
Accepted
11 May 2015
First published
12 May 2015

Chem. Commun., 2015,51, 10111-10114

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Cationic dinuclear platinum and palladium complexes with bridging hydrogermylene and hydrido ligands

N. Nakata, N. Sekizawa and A. Ishii, Chem. Commun., 2015, 51, 10111 DOI: 10.1039/C5CC03062E

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