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Issue 43, 2015
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Enantioselective adsorption in homochiral metal–organic frameworks: the pore size influence

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Abstract

Uptake experiments in thin films of isoreticular chiral MOFs of type Cu2(Dcam)2(L) with identical stereogenic centers but different pore dimensions show that the enantioselectivity is significantly influenced by the pore size. The highest selectivity was found for medium pore sizes, roughly corresponding to the extension of the chiral guest molecule, limonene.

Graphical abstract: Enantioselective adsorption in homochiral metal–organic frameworks: the pore size influence

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Publication details

The article was received on 01 Apr 2015, accepted on 28 Apr 2015 and first published on 29 Apr 2015


Article type: Communication
DOI: 10.1039/C5CC02706C
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Chem. Commun., 2015,51, 8998-9001

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    Enantioselective adsorption in homochiral metal–organic frameworks: the pore size influence

    Z. Gu, S. Grosjean, S. Bräse, C. Wöll and L. Heinke, Chem. Commun., 2015, 51, 8998
    DOI: 10.1039/C5CC02706C

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