Preparation of silver triazolylidene (trz) species from triazolium salts and Ag2O in refluxing MeCN leads to a selective C–C bond cleavage and the formation of complexes of general formula [(trz)Ag(CN)] from Calkyl–CN bond activation. Moreover, these silver carbene complexes are precursors of highly active catalysts for oxazoline formation via aldol condensation.
R. Heath, H. Müller-Bunz and M. Albrecht, Chem. Commun., 2015, 51, 8699 DOI: 10.1039/C5CC02558C
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