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Issue 49, 2015
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Polyhomologation based on in situ generated boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architectures

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Abstract

A novel strategy, based on the in situ generated boron-thexyl-silaboracyclic initiating sites for the polyhomologation of dimethylsulfoxonium methylide, has been developed for the synthesis of complex polyethylene-based architectures. As examples, the synthesis of a 4-arm polyethylene star, three (polystyrene)(polyethylene)2 3-miktoarm stars and a PE-branched double graft copolymer is given.

Graphical abstract: Polyhomologation based on in situ generated boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architectures

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Article information


Submitted
21 Feb 2015
Accepted
10 Apr 2015
First published
10 Apr 2015

This article is Open Access

Chem. Commun., 2015,51, 9936-9938
Article type
Communication
Author version available

Polyhomologation based on in situ generated boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architectures

Z. Zhang, H. Zhang, Y. Gnanou and N. Hadjichristidis, Chem. Commun., 2015, 51, 9936
DOI: 10.1039/C5CC01579K

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