Cascade upgrading of γ-valerolactone (GVL), produced from renewable cellulosic biomass, with selective conversion to biofuels pentyl valerate (PV) and pentane in one pot using a bifunctional Pd/HY catalyst is described. Excellent catalytic performance (over 99% conversion of GVL, 60.6% yield of PV and 22.9% yield of pentane) was achieved in one step. These biofuels can be targeted for gasoline and jet fuel applications.
K. Yan, T. Lafleur, X. Wu, J. Chai, G. Wu and X. Xie, Chem. Commun., 2015, 51, 6984 DOI: 10.1039/C5CC01463H
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