Issue 24, 2015

A pyrazolate-stabilized sodium hydride complex

Abstract

The reaction of a sterically demanding sodium pyrazolate complex with n-butylsodium and diphenylsilane afforded the first well-defined molecular sodium hydride complex [(pz)6Na7H] 1 (pz = 3,5-di-tert-butylpyrazolate) that could be structurally characterised.

Graphical abstract: A pyrazolate-stabilized sodium hydride complex

Supplementary files

Article information

Article type
Communication
Submitted
03 Feb 2015
Accepted
11 Feb 2015
First published
12 Feb 2015

Chem. Commun., 2015,51, 5056-5058

Author version available

A pyrazolate-stabilized sodium hydride complex

A. Stasch, Chem. Commun., 2015, 51, 5056 DOI: 10.1039/C5CC00996K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements