The reaction of a sterically demanding sodium pyrazolate complex with n-butylsodium and diphenylsilane afforded the first well-defined molecular sodium hydride complex [(pz)6Na7H] 1 (pz = 3,5-di-tert-butylpyrazolate) that could be structurally characterised.
A. Stasch, Chem. Commun., 2015, 51, 5056 DOI: 10.1039/C5CC00996K
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