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Issue 27, 2015
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Lewis-acid induced disaggregation of dimeric arylantimony oxides

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Abstract

The previously known dimeric arylantimony oxides (Ph3SbO)2 and [2,6-(Me2NCH2)2C6H3SbO]2 were disaggregated by the Lewis acid B(C6F5)3 giving rise to the formation of the Lewis pair complexes Ph3SbOB(C6F5)3 and 2,6-(Me2NCH2)2C6H3SbOB(C6F5)3 having short bipolar single Sb–O bonds.

Graphical abstract: Lewis-acid induced disaggregation of dimeric arylantimony oxides

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Publication details

The article was received on 26 Jan 2015, accepted on 20 Feb 2015 and first published on 23 Feb 2015


Article type: Communication
DOI: 10.1039/C5CC00738K
Citation: Chem. Commun., 2015,51, 5932-5935
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    Lewis-acid induced disaggregation of dimeric arylantimony oxides

    R. Kather, T. Svoboda, M. Wehrhahn, E. Rychagova, E. Lork, L. Dostál, S. Ketkov and J. Beckmann, Chem. Commun., 2015, 51, 5932
    DOI: 10.1039/C5CC00738K

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