Issue 18, 2015

Diastereoselective synthesis of O symmetric heterometallic cubic cages

Abstract

Enantiopure chiral cubic cages have been diastereoselectively synthesized for the first time. Chiral amines lead to the isolation of O symmetric homochiral cubic cages, while an achiral amine gives a racemic mixture. CD enhancement is observed as a result of configuration rigidity.

Graphical abstract: Diastereoselective synthesis of O symmetric heterometallic cubic cages

Supplementary files

Article information

Article type
Communication
Submitted
06 Jan 2015
Accepted
27 Jan 2015
First published
27 Jan 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 3804-3807

Diastereoselective synthesis of O symmetric heterometallic cubic cages

Y. Yang, J. Jia, X. Pei, H. Zheng, Z. Nan and Q. Wang, Chem. Commun., 2015, 51, 3804 DOI: 10.1039/C5CC00087D

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