Issue 27, 2015
From the journal:

Chemical Communications

Template-directed construction of conformational supramolecular isomers for bilayer porous metal–organic frameworks with distinct gas sorption behaviors†

Min Chen,a   Hui Zhao,a   Chun-Sen Liu,a   Xi Wang,ab   Heng-Zhen Shi*a  and  Miao Du ORCID logo *ab  

* Corresponding authors

a Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002, P. R. China
E-mail: shihz@zzuli.edu.cn

b College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Tianjin Normal University, Tianjin 300387, China
E-mail: dumiao@public.tpt.tj.cn

Abstract

A pair of supramolecular isomers of Co(II)-based metal–organic frameworks can be directionally constructed in virtue of solvent templates, which show diverse bilayer networks and lattice packing with the same Co3 SBUs and organic linkers. The two porous materials show distinct gas sorption behaviors at different temperatures, especially their CO2 sorption selectivity.

Graphical abstract: Template-directed construction of conformational supramolecular isomers for bilayer porous metal–organic frameworks with distinct gas sorption behaviors

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Article information

DOI
https://doi.org/10.1039/C5CC00018A
Article type
Communication
Submitted
02 Jan 2015
Accepted
25 Feb 2015
First published
25 Feb 2015

Chem. Commun., 2015,51, 6014-6017

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Template-directed construction of conformational supramolecular isomers for bilayer porous metal–organic frameworks with distinct gas sorption behaviors

M. Chen, H. Zhao, C. Liu, X. Wang, H. Shi and M. Du, Chem. Commun., 2015, 51, 6014 DOI: 10.1039/C5CC00018A

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