Issue 26, 2015
From the journal:

Chemical Communications

Facile thermodynamic conversion of a linear metallopolymer into a self-assembled hexameric metallomacrocycle†

Yiming Li,a   Zhilong Jiang,a   Jie Yuan,a   Die Liu,a   Tun Wu,a   Charles N. Moorefield,b   George R. Newkomeb  and  Pingshan Wang*a  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Central South University, Changsha-410083, Hunan, P. R. China
E-mail: chemwps@csu.edu.cn
Fax: +86-731 888796161

b Departments of Polymer Science, Maurice Morton Institute of Polymer Science, Department of Polymer Engineering and Chemistry, The University of Akron, Akron, OH 44325-4717, USA

Abstract

The initial metallopolymer, derived from two different organic building blocks, is a kinetic intermediate to the final stable hexanuclear (bearing 4Ru2+ and 2Fe2+) metallomacrocycle obtained through a thermodynamic dis-assembly/re-assembly route. The heteroleptic metallomacrocyclic architecture was characterized by NMR, UV, IR, CV, 2D-ROESY, DOSY, and ESI-MS.

Graphical abstract: Facile thermodynamic conversion of a linear metallopolymer into a self-assembled hexameric metallomacrocycle

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Article information

DOI
https://doi.org/10.1039/C4CC10361K
Article type
Communication
Submitted
28 Dec 2014
Accepted
20 Feb 2015
First published
20 Feb 2015

Chem. Commun., 2015,51, 5766-5769

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Facile thermodynamic conversion of a linear metallopolymer into a self-assembled hexameric metallomacrocycle

Y. Li, Z. Jiang, J. Yuan, D. Liu, T. Wu, C. N. Moorefield, G. R. Newkome and P. Wang, Chem. Commun., 2015, 51, 5766 DOI: 10.1039/C4CC10361K

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