Issue 27, 2015
From the journal:

Chemical Communications

Synthesis of 3-bromosubstituted pyrroles via palladium-catalyzed intermolecular oxidative cyclization of bromoalkynes with N-allylamines†

Jia Zheng,a   Liangbin Huang,a   Zun Li,a   Wanqing Wu,a   Jianxiao Lia  and  Huanfeng Jiang*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
E-mail: jianghf@scut.edu.cn
Fax: +86-20-87112906
Tel: +86-20-87112906

Abstract

This paper describes a novel palladium-catalyzed oxidative cyclization of bromoalkynes with N-allylamines via cascade formation of C–N and C–C bonds. During this process, the bromine atom was retained to form 3-bromo-pyrroles, which can undergo the subsequent structural modifications.

Graphical abstract: Synthesis of 3-bromosubstituted pyrroles via palladium-catalyzed intermolecular oxidative cyclization of bromoalkynes with N-allylamines

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Article information

DOI
https://doi.org/10.1039/C4CC10322J
Article type
Communication
Submitted
26 Dec 2014
Accepted
20 Feb 2015
First published
20 Feb 2015

Chem. Commun., 2015,51, 5894-5897

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Synthesis of 3-bromosubstituted pyrroles via palladium-catalyzed intermolecular oxidative cyclization of bromoalkynes with N-allylamines

J. Zheng, L. Huang, Z. Li, W. Wu, J. Li and H. Jiang, Chem. Commun., 2015, 51, 5894 DOI: 10.1039/C4CC10322J

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