Issue 23, 2015
From the journal:

Chemical Communications

Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration†

Hong-Li Huang,a   Hang Yan,a   Chao Yang*a  and  Wujiong Xia*a  

* Corresponding authors

a State Key Lab of Urban Water Resource and Environment, the Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150080, China
E-mail: xyyang@hit.edu.cn, xiawj@hit.edu.cn
Fax: +86-451-86403760

Abstract

A photocatalytic process for selective arylalkylation of allylic alcohols with α-bromo diethyl malonate has been developed. The reaction provided a straightforward approach to synthesize α-aryl-β-alkylated ketones via unique 1,2-aryl migration. The procedure is highlighted by its operational simplicity and mild reaction conditions.

Graphical abstract: Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration

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Article information

DOI
https://doi.org/10.1039/C4CC10321A
Article type
Communication
Submitted
26 Dec 2014
Accepted
10 Feb 2015
First published
13 Feb 2015

Chem. Commun., 2015,51, 4910-4913

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Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration

H. Huang, H. Yan, C. Yang and W. Xia, Chem. Commun., 2015, 51, 4910 DOI: 10.1039/C4CC10321A

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