Issue 18, 2015
From the journal:

Chemical Communications

Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers†

José Manuel Villalba Franco,a   Takahiro Sasamori,b   Gregor Schnakenburg,a   Arturo Espinosa Ferao*c  and  Rainer Streubel*a  

* Corresponding authors

a Institut für Anorganische Chemie der Reinischen Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Str.1, 53121 Bonn, Germany
E-mail: r.streubel@uni-bonn.de
Fax: +49 228 739616
Tel: +49 228 735345

b Institut for Chemical Research, Kyoto University, Gokasho Uji, Kyoto, Japan

c Departamento de Química Orgánica, Universidad de Murcia, Campus de Espinardo, 30100 Murcia, Spain
E-mail: artuesp@um.es

Abstract

Reaction of a Li/Cl phosphinidenoid complex with N,N′-dialkyl carbodiimides yielded the novel 3-imino-azaphosphiridine complexes; reaction with water led selectively to the first stable valence isomer of an oxaphosphirane complex.

Graphical abstract: Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers

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Article information

DOI
https://doi.org/10.1039/C4CC10266E
Article type
Communication
Submitted
23 Dec 2014
Accepted
29 Jan 2015
First published
06 Feb 2015

Chem. Commun., 2015,51, 3878-3881

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Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers

J. M. Villalba Franco, T. Sasamori, G. Schnakenburg, A. Espinosa Ferao and R. Streubel, Chem. Commun., 2015, 51, 3878 DOI: 10.1039/C4CC10266E

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