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Issue 31, 2015
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9,9′-Anthryl-anthroxyl radicals: strategic stabilization of highly reactive phenoxyl radicals

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Abstract

Stable 9,9′-anthryl-anthroxyl radicals were synthesized and isolated, and the structures were fully characterized by single crystal X-ray diffraction analysis and ESR measurement. The resonance structure and steric protection of the peripheral positions and the most reactive 9-position of anthracene prolong the half-life of the radical in solution to 11 days.

Graphical abstract: 9,9′-Anthryl-anthroxyl radicals: strategic stabilization of highly reactive phenoxyl radicals

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Submitted
18 Dec 2014
Accepted
27 Jan 2015
First published
13 Feb 2015

Chem. Commun., 2015,51, 6734-6737
Article type
Communication

9,9′-Anthryl-anthroxyl radicals: strategic stabilization of highly reactive phenoxyl radicals

T. Aotake, M. Suzuki, N. Aratani, J. Yuasa, D. Kuzuhara, H. Hayashi, H. Nakano, T. Kawai, J. Wu and H. Yamada, Chem. Commun., 2015, 51, 6734
DOI: 10.1039/C4CC10104A

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