Mirror symmetry breaking upon spontaneous crystallization from a dynamic combinatorial library of macrocyclic imines†
Abstract
Spontaneous emergence of solid state chirality and mirror symmetry breaking occurred upon crystallization from a small templated dynamic combinatorial library (DCL) of achiral macrocyclic imines, and depended strongly on the nature of library building blocks (amines, aldehydes, template cations and anions) and crystallization temperature.
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