Issue 26, 2015

Asymmetric hydroamination catalyzed by a new chiral zirconium system: reaction scope and mechanism

Abstract

A new class of chiral zirconium complexes supported by chiral tridentate [ONO]-type of ligands derived from amino acids were synthesized and structurally characterized. They catalyzed asymmetric hydroamination/cyclization of primary aminoalkenes to give five- and six-membered N-heterocyclic amines with up to 94% ee.

Graphical abstract: Asymmetric hydroamination catalyzed by a new chiral zirconium system: reaction scope and mechanism

Supplementary files

Article information

Article type
Communication
Submitted
16 Dec 2014
Accepted
19 Feb 2015
First published
19 Feb 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 5751-5753

Asymmetric hydroamination catalyzed by a new chiral zirconium system: reaction scope and mechanism

X. Zhou, B. Wei, X. Sun, Y. Tang and Z. Xie, Chem. Commun., 2015, 51, 5751 DOI: 10.1039/C4CC10032H

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements