Issue 18, 2015

Reductive arene ortho-silanolization of aromatic esters with hydridosilyl acetals

Abstract

This work describes the design and application of a single-pot, reductive arene C–H silanolization of aromatic esters for synthesis of ortho-formyl arylsilanols. This strategy involves a sequence of two transition metal (Ir and Rh)-catalyzed reactions for reductive arene ortho-silylation directed by hydridosilyl acetals and hydrolysis.

Graphical abstract: Reductive arene ortho-silanolization of aromatic esters with hydridosilyl acetals

Supplementary files

Article information

Article type
Communication
Submitted
09 Dec 2014
Accepted
27 Jan 2015
First published
27 Jan 2015

Chem. Commun., 2015,51, 3778-3781

Author version available

Reductive arene ortho-silanolization of aromatic esters with hydridosilyl acetals

Y. Hua, P. Asgari, U. S. Dakarapu and J. Jeon, Chem. Commun., 2015, 51, 3778 DOI: 10.1039/C4CC09850A

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