Issue 32, 2015

Self-assembling triazolophanes: from croissants through donuts to spherical vesicles

Abstract

Macrocyclic compounds M1–M3 with different ring sizes containing amide and triazole units were synthesized. These triazolophanes displayed a variety of self-assembled structures such as hemi-toroids, toroids, and vesicles in a concentration dependent manner. Detailed ultramicroscopic and crystallographic investigations delineated a hierarchical mechanism of self-assembly.

Graphical abstract: Self-assembling triazolophanes: from croissants through donuts to spherical vesicles

Supplementary files

Article information

Article type
Communication
Submitted
01 Dec 2014
Accepted
11 Feb 2015
First published
11 Feb 2015

Chem. Commun., 2015,51, 6905-6908

Author version available

Self-assembling triazolophanes: from croissants through donuts to spherical vesicles

V. Haridas, A. R. Sapala and J. P. Jasinski, Chem. Commun., 2015, 51, 6905 DOI: 10.1039/C4CC09587A

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