Issue 13, 2015
From the journal:

Chemical Communications

A fluorescent heteroditopic hemicryptophane cage for the selective recognition of choline phosphate†

Dawei Zhang,ab   Guohua Gao,*a   Laure Guy,b   Vincent Robert,c   Jean-Pierre Dutasta*b  and  Alexandre Martinez*bd  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai, P. R. China
E-mail: ghgao@chem.ecnu.edu.cn

b Laboratoire de Chimie, CNRS, École Normale Supérieure de Lyon, 46, Allée d’Italie, F-69364 Lyon, France
E-mail: jean-pierre.dutasta@ens-lyon.fr, alexandre.martinez@ens-lyon.fr

c Laboratoire de Chimie Quantique Institut de Chimie, UMR CNRS 7177, Université de Strasbourg, 4, rue Blaise Pascal, F-67070 Strasbourg, France

d Equipe Chirosciences, UMR CNRS 7313-iSm2, Aix Marseille Université, Ecole Centrale de Marseille, Av. Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France

Abstract

The first fluorescent hemicryptophane cage was synthesized and developed as an efficient and selective sensor for choline phosphate. The heteroditopic character of the host in the recognition process was evidenced. NMR experiments highlight a full encapsulation of the guest, inducing the chiralisation-like behavior of the achiral choline phosphate.

Graphical abstract: A fluorescent heteroditopic hemicryptophane cage for the selective recognition of choline phosphate

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Article information

DOI
https://doi.org/10.1039/C4CC09428J
Article type
Communication
Submitted
25 Nov 2014
Accepted
20 Dec 2014
First published
23 Dec 2014

Chem. Commun., 2015,51, 2679-2682

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A fluorescent heteroditopic hemicryptophane cage for the selective recognition of choline phosphate

D. Zhang, G. Gao, L. Guy, V. Robert, J. Dutasta and A. Martinez, Chem. Commun., 2015, 51, 2679 DOI: 10.1039/C4CC09428J

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